The sinking of crystals through a viscid substance like molten rock, as is unequivocally shown to have been the case in the experiments of M.Dree, is worthy of further consideration, as throwing light on the separation of the trachytic and basaltic series of lavas.Mr.P.Scrope has speculated on this subject; but he does not seem to have been aware of any positive facts, such as those above given; and he has overlooked one very necessary element, as it appears to me, in the phenomenon--namely, the existence of either the lighter or heavier mineral in globules or in crystals.In a substance of imperfect fluidity, like molten rock, it is hardly credible, that the separate, infinitely small atoms, whether of feldspar, augite, or of any other mineral, would have power from their slightly different gravities to overcome the friction caused by their movement; but if the atoms of any one of these minerals became, whilst the others remained fluid, united into crystals or granules, it is easy to perceive that from the lessened friction, their sinking or floating power would be greatly increased.On the other hand, if all the minerals became granulated at the same time, it is scarcely possible, from their mutual resistance, that any separation could take place.A valuable, practical discovery, illustrating the effect of the granulation of one element in a fluid mass, in aiding its separation, has lately been made: when lead containing a small proportion of silver, is constantly stirred whilst cooling, it becomes granulated, and the grains of imperfect crystals of nearly pure lead sink to the bottom, leaving a residue of melted metal much richer in silver; whereas if the mixture be left undisturbed, although kept fluid for a length of time, the two metals show no signs of separating.(A full and interesting account of this discovery, by Mr.Pattinson, was read before the British Association in September 1838.In some alloys, according to Turner "Chemistry" page 210, the heaviest metal sinks, and it appears that this takes place whilst both metals are fluid.Where there is a considerable difference in gravity, as between iron and the slag formed during the fusion of the ore, we need not be surprised at the atoms separating, without either substance being granulated.) The sole use of the stirring seems to be, the formation of detached granules.The specific gravity of silver is 10.4, and of lead 11.35: the granulated lead, which sinks, is never absolutely pure, and the residual fluid metal contains, when richest, only 1/119 part of silver.As the difference in specific gravity, caused by the different proportions of the two metals, is so exceedingly small, the separation is probably aided in a great degree by the difference in gravity between the lead, when granular though still hot, and when fluid.
In a body of liquified volcanic rock, left for some time without any violent disturbance, we might expect, in accordance with the above facts, that if one of the constituent minerals became aggregated into crystals or granules, or had been enveloped in this state from some previously existing mass, such crystals or granules would rise or sink, according to their specific gravity.Now we have plain evidence of crystals being embedded in many lavas, whilst the paste or basis has continued fluid.I need only refer, as instances, to the several, great, pseudo-porphyritic streams at the Galapagos Islands, and to the trachytic streams in many parts of the world, in which we find crystals of feldspar bent and broken by the movement of the surrounding, semi-fluid matter.Lavas are chiefly composed of three varieties of feldspar, varying in specific gravity from 2.4 to 2.74; of hornblende and augite, varying from 3.0 to 3.4; of olivine, varying from 3.3 to 3.4; and lastly, of oxides of iron, with specific gravities from 4.8 to 5.2.Hence crystals of feldspar, enveloped in a mass of liquified, but not highly vesicular lava, would tend to rise to the upper parts; and crystals or granules of the other minerals, thus enveloped, would tend to sink.We ought not, however, to expect any perfect degree of separation in such viscid materials.Trachyte, which consists chiefly of feldspar, with some hornblende and oxide of iron, has a specific gravity of about 2.45; whilst basalt, composed chiefly of augite and feldspar, often with much iron and olivine, has a gravity of about 3.0.
